Passivation does not coat anything. It removes the free iron left by machining, lapping and handling, and lets the stainless steel rebuild its own chromium oxide layer.
| Thickness | 0 µm — a chemical treatment, not a coating |
|---|---|
| Mechanism | Dissolves free iron; chromium oxide layer re-forms |
| Acids | Citric (safer, widely accepted) or nitric (traditional, ASTM A967) |
| Effect on dimension | None |
| Max service temperature | n/a — the steel's own limit applies |
| Standards | ASTM A967 / AMS 2700 |
| Typical use | 440C and 316 bearing rings, machined parts, welded assemblies |
Stainless resists corrosion because chromium at the surface reacts with oxygen to form a passive oxide layer a few nanometres thick. Machining, lapping, blasting and even handling with carbon-steel tools embed free iron particles in the surface. Those particles rust, and the rust stain looks like a material failure even though the alloy is correct.
Passivation removes that free iron. It does not remove scale, weld discolouration or embedded particles of a different alloy — those need pickling or mechanical cleaning first. The two processes are often confused; pickling dissolves scale, passivation removes free iron.
| Property | Passivation | Pickling | Electropolishing |
|---|---|---|---|
| Removes free iron | Yes | Yes | Yes |
| Removes scale / heat tint | No | Yes | Partly |
| Material removed | None measurable | Some | 5–25 µm |
| Changes dimension | No | Slightly | Yes |
| Standards | ASTM A967 / AMS 2700 | ASTM A380 | ASTM B912 |
The grade most often passivated after grinding.
Read →Marine and chemical parts after machining or welding.
Read →Rust on a “stainless” bearing is often a passivation issue, not a fake.
Read →The equivalent treatment where the part is not stainless.
Read →No. It removes free iron at a microscopic level and adds nothing. It is the only “finish” here that is dimensionally neutral.
Almost always free iron contamination from machining or handling, or service in chlorides. Passivation fixes the first; nothing fixes the second except a different material.
Passivation for free iron removal with no dimensional change. Electropolishing if the surface must also be brightened or deburred at a microscopic level, and a small dimensional change is acceptable.
The water-break test (a film of water should stay unbroken for 30 seconds) or the copper sulphate test for free iron. Both are quick and should be part of the specification.
Model numbers, quantities and the application — we reply with brand options, price and lead time within 30 minutes on working days.