Black oxide is the finish you use when the part must look right, stay dimensionally identical, and resist handling and condensation — not salt water.
| Thickness | 1–3 µm (conversion layer, not a deposit) |
|---|---|
| Salt spray | 24–72 h when oiled · a few hours dry |
| Max service temperature | ≈200 °C (the oil film is the limit) |
| Effect on dimension | Negligible — the layer grows into the surface as well as out |
| Appearance | Matt to satin black |
| RoHS / REACH | Compliant; hot blackening baths are caustic, not chromate |
| Typical use | Bearing rings, exposed steel parts, tools, fixturing |
The part is immersed in a hot alkaline oxidising bath, and the surface steel reacts to form magnetite (Fe3O4). Because the layer consumes some of the base metal and grows partly inward, the external dimension changes by well under a micrometre in most cases — which is why it is the finish of choice for parts whose tolerances cannot absorb a deposit.
On its own, black oxide is a poor corrosion barrier: it is thin and slightly porous. Its performance comes from the oil, wax or dry-film that is applied afterwards, which fills the pores. That is why the specification must state the post-treatment, not just “black oxide”.
| Property | Black oxide | Manganese phosphate | Zinc plating |
|---|---|---|---|
| Thickness | 1–3 µm | 5–15 µm | 5–8 µm |
| Salt spray (oiled) | 24–72 h | 24–96 h | 96–240 h |
| Dimensional change | Negligible | Moderate | Significant |
| Friction | Slight reduction with oil | Lowers, retains oil | None |
| Appearance | Black | Dark grey | Bright / yellow |
| Best for | Tight tolerance, appearance | Running-in, oil retention | Corrosion |
Dimension-critical parts that must not change size.
Read →Appearance and handling protection without a dimensional penalty.
Read →When the surface must also retain oil and aid running-in.
Read →The equivalent treatment for 440C and 316 parts.
Read →By less than a micrometre in practice. The layer partly grows into the base metal, so it is the standard choice where a deposit would consume the tolerance.
No. It resists handling and condensation for a while, especially when oiled, but it is not a corrosion barrier. For salt or water, use zinc-nickel or a stainless grade.
Not in the same way. Stainless is passivated instead; there are blackening processes for stainless but they are different chemistries and much less common on bearings.
Surface condition before processing — scale, machining marks and different alloys take the conversion at different rates. A uniform surface preparation is what makes a uniform colour.
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